Soil Pollution

Pollutants

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Phosphorus on the Farm

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            Pesticides           
Over 900 types, in 60,000 formulations

  Insecticides     -     most applied to crops; nematocides applied to soils

 

(1/2 life)

LD50 (rat)

 

(mg/kg BW)

  Chlorinated hydrocarbons     -    bioaccumulate/banned - very persistent
                                                            nonpolar, water insoluble, adsorb to OM: London forces
     

DDT

5 yr

113

     

Lindane

3 yr

125

     

Heptachlor

2 yr

100

     

Dieldrin

1 yr

39

     

Aldrin

1 yr

40

 

Organophosphates    -    Replaced Organochlorines, very toxic, not persistent
                                               Polar bonds, water soluble, adsorb by dipole-dipole

     

Parathion

1-12 wk

4

     

Malathion

1-12 wk

1,000

     

Diazinon

1-12 wk

300

 

Carbamates    -    Replaced Organochlorines, very toxic, not persistent
                                Polar bonds, water soluble, adsorb by dipole-dipole or exchange

     

Carbaryl (Sevin)

1-8 wk

500

     

Temik

1-8 wk

1

 

Pyrethrium

       
 

Inorganics

 

Lead Arsenate

forever

 

  Fungicides

 

thiocarbamates

 

ferbam

   
 

mercurials

 

ceresan

Hg forever

 
 

others

 

copper sulfate

Cu forever

 

  Herbicides    -    used more than other two combined

 

phenoxyalkyl acids

2,4-D

6 mo.

370

 

(aka chlorophenoxy acids)

2,4,5-T

1-5 mo

500

 

triazines (most used)

atrazine

1-2 yr

3,000

     

simazine

1-2 yr

5,000

 

phenylureas

 

linuron

2-10 mo

 
 

aliphatic acids

 

dalapon

   
 

carbamates

 

butylate

2-8 wk

 
 

dinitroanilines

 

triflualin

   
 

dipyridyl

 

paraquat, diquat

   
 

amides

 

alachlor

   
 

benzoics

 

dicambra

2-12 mo