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Graphite Furnace AAS |
Advantages
of GFAAS
aka Electrothermal
Vaporization

1. More sensitive than Flame AAS
Pb in flame = 100 ppb
Pb in Furnace = 0.1 ppb
Isolates larger population
of atoms in light
path
2. More
elements
- especially
transition elements
Higher temp.
(Flame - 1,700oC)
(Electrothermal Vaporization 1,200 - 3,000oC)
More e- go to excited state at high temp's; higher sensitivity