Graphite Furnace AAS

Advantages

Disadvantages

Components

Temp. Program

Matrix Modifiers

BackgroundCorrection

Advantages of GFAAS
aka Electrothermal Vaporization

            1.  More sensitive than Flame AAS

                            Pb in flame      =  100 ppb
                            Pb in Furnace    =  0.1 ppb
                       Isolates larger population of atoms in light path

                     2.  More elements  -  especially transition elements

                      
Higher temp.  (Flame - 1,700oC)
                                         (Electrothermal Vaporization   1,200 -
3,000oC)

                        More e- go to excited state at high temp's;  higher sensitivity